dc.contributor.supervisor |
Akinyemi, Felicia, O. |
|
dc.contributor.supervisor |
Eze, Peter N. |
|
dc.contributor.author |
Kebonye, Ndiye Michael |
|
dc.date.accessioned |
2019-01-29T14:33:31Z |
|
dc.date.available |
2019-01-29T14:33:31Z |
|
dc.date.issued |
2017-09 |
|
dc.identifier.citation |
Kebonye, Ndiye Michael (2017)Impact assessment of long term treated wastewater discharge on heavy metal concentration in soils from Palapye east, Botswana , Masters Theses, Botswana International University of Science and Technology: Palapye |
en_US |
dc.identifier.uri |
https://repository.biust.ac.bw/handle/123456789/41 |
|
dc.description |
Theses (MSc-Environmental Sciences)----Botswana International University of Science and Technology, 2017 |
en_US |
dc.description.abstract |
Issues on environmental soil quality continue to attract much global attention. Domestic
wastewater is a potential source of contaminants capable of degrading the soil environment.
This study reports the accumulative effects of 21 years (1995 – 2016) of treated wastewater
discharge on heavy metal concentration levels in the proximal environment of Palapye
wastewater treatment Plant (PWTP), Central Botswana. Soil samples were collected from
eight geo-referenced pedons: four situated along the treated wastewater channel and four on
an adjacent well-drained channel (control). Selected physico-chemical properties of the soils
were determined using routine laboratory procedures and heavy metal concentrations with
portable XRF (Olympus Delta Premium Analyser SN: 550255, USA). Results of the study
show that heavy metal (Fe, Cu, Zn, Mn, Pb and U) concentrations in the two drainage classes (poorly drained and somewhat excessively drained) did not vary significantly (p > 0.05).
There was strong correlation between organic matter (OM) and Fe (R2 = 0.896, p < 0.01),
OM and Cu (R2 = 0.908, p < 0.01), OM and Zn (R2 = 0.956, p < 0.01) and OM and Mn (R2 =
0.954, p < 0.01) in control soils, while treated wastewater affected soils showed strong
correlation for OM and Fe (R2 = 0.765, p < 0.01), OM and Zn (R2 = 0.770, p < 0.01) and OM
and Mn (R2 = 0.802, p < 0.01). Source apportionment of heavy metals using PCA shows one
component in the control soils accounted for 77% of the total variance, while two
components accounted for 97% of the total variance in treated wastewater affected soils.
Geochemical mass balance plots for selected profiles showed fluctuations for Fe and Mn at
various depths while Zn maintained an almost constant trend. The geoaccumulation (Igeo) and pollution load (PLI) indices both show all soils to be unpolluted. Conclusion is made that
two decades of treated wastewater discharge has not led to the degradation of environmental
soil quality in Palapye. However, it is strongly recommended that heavy metal levels be checked intermittently as a routine environmental monitoring exercise. Manganese which
showed severe enrichment in two profiles 7 and 8 might indicates possible soil pollution, but
their speciation and bio-accessibility, rather than simply total concentrations, have to be
established. |
en_US |
dc.language.iso |
en |
en_US |
dc.publisher |
Botswana International University of Science and Technology |
en_US |
dc.subject |
Agriculture |
en_US |
dc.subject |
Entisols |
en_US |
dc.subject |
Palapye Wastewater Treatment Plant |
en_US |
dc.subject |
Portable XRF |
en_US |
dc.subject |
Soil |
en_US |
dc.title |
Impact assessment of long term treated wastewater discharge on heavy metal concentration in soils from Palapye east, Botswana |
en_US |
dc.description.level |
msc |
en_US |
dc.description.accessibility |
unrestricted |
en_US |
dc.description.department |
ees |
en_US |